New Active Materials for Lithium Batteries - Some Examples
Jerry Barker has invented several new classes of
electroactive materials. Please follow the hyperlinks below to find more
information below some of these materials.
»Li3M2(PO4)3 Active
Materials
»Silicophosphate Active Materials
»LiMPO4F Active
Materials
»LiMPO4.OH Active Materials
»LiFe(M)PO4 Active
Materials
»Li2MPO4F Active
Materials
»Na2MPO4F Active
Materials
»Na3M2(PO4)2F3 Active Materials
»Sulfate Active
Materials
»Li2MTiO4 Active
Materials
»LiMTiO4 Active
Materials
»LixMoO2 Active
Materials
»Surface-Stabilized LiMn2O4
»Li2CuO2 Active Material
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Background Information
The development of advanced materials in electrochemistry may
be described as an enabling technology. These novel materials will help revolutionize the performance characteristics
of electrochemical applications such as lithium ion batteries,
photovoltaics devices, electrochromic displays, electro-optic
devices and many others. The development of these advanced materials requires a highly
technical background and relevant experience, but most
significantly relies on an innovative approach.
Jerry Barker has a proven track record of
new material innovation. Not only is he the named inventor on several high profile
patents covering advanced materials, but he is also widely acknowledged as a world leader in the development of advanced
electrode materials for lithium-ion applications. Let our organization assist
you to create and protect your own advanced
materials program.
Lithium-ion battery materials may serve as an example of the
impact of advanced materials. Until recently only a limited
number of cathode-active materials for lithium ion batteries have
been commercially available – i.e. those based on cobalt, nickel and manganese
oxides. The
commercial application of lithium
cobalt oxide has been particularly successful. However, these
oxide-based materials have some distinct and important
disadvantages – for example, high cost, toxicity, safety concerns and limited specific
capacity – thus creating a requirement for alternative and
improved electroactive materials.
Recently, polyanion-based cathode materials (e.g. phosphates,
fluorophosphates, sulfates, fluorosulfates etc.) have been proposed for incorporation as electrode
materials in lithium ion batteries. These new materials have
some significant advantages over their oxide-based
counterparts. It is expected that these polyanion compounds will
be a commercial reality in the near future, enabling production of
the 'next generation’ of lithium ion batteries. Dr. Barker has
been actively involved at the forefront of this work for many
years and is considered to be a pioneer of phosphate and
polyanion-based electroactive materials for the battery industry. More specifically he is the named inventor on
several high profile US and European patents (both issued and
pending) describing the properties of these next generation
materials. For more information on these issued patents please
view our
Patents and Intellectual Property page.
The discovery of the polyanion type materials has clearly
demonstrated the impact of novel electroactive materials. We at
Jerry Barker Consultants are of little doubt that other novel
electroactive materials will soon be discovered and believe
strongly that these new compounds may help revolutionize current lithium ion
technology. This creative process will mean the next generation
of lithium ion technology is a reality, providing batteries with
unrivalled cost and performance. Clearly Dr. Barker has a
wealth of knowledge and expertise in this area and as an
organization, we are ready and able to assist you in the search
and development of these enabling materials.
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Advanced Active Materials for Battery Applications - IP
The
discovery of novel
advanced materials is considered the key to
improving the performance of
electrochemical systems. For example, the discovery and development of new
electrode materials will significantly enhance the energy density, power
capability and safety
characteristics of lithium-ion
batteries. In addition problems
associated with developing
scalable manufacturing
methods for these materials
will also need to be addressed.
Below is a brief summary of the different
active materials in which Jerry Barker is either sole inventor or
co-inventor. In each case, an example issued US patent or US patent
application is included.
LiFe1-xMxPO4 Substituted
Olivines (M = Mg, Ca, Zn etc.) US 6884544
Li3M2(PO4)3 Nasicons (M = Fe, V, Mn etc.) US 5871866
LiMPO4F Fluorophosphates (M = Fe, V, Mn etc.) US 6387568
LiMPO4.OH Hydroxy-phosphates (M = Fe, V, Mn etc.) US
6777132
Li2MP2O7 Dilithium diphosphates (M = Fe, Mn, Co, Ni etc.)
US 7008566
Li3M(SO4)3 Lithium sulfates (M = Fe, V, Mn etc.) US 5908716
LiMSO4F Lithium Fluorosulfates (M = Fe, Mn, Co, Ni etc.) US
2005/0163699
NaMSO4F Sodium Fluorosulfates (M = Fe, Mn, Co, Ni etc.) US
2005/0163699
Li2MPO4F Lithium Fluorophosphates (M = Fe, Mn, Co, Ni etc.)
US 6890686
Na2MPO4F Sodium Fluorophosphates (M = Fe, Mn, Co, Ni etc.)
US 6890686
Li4M2(SiO4)(PO4)2 Silicophosphates (M = Fe, V, Mn etc.) US
6136472
Li3M1.5Al0.5(PO4)3 Substituted Nasicons (M = Fe, V, Mn
etc.) US 5871866
β-LiVOPO4 Vanadyl Phosphate US 6645452 (method-of-making)
NaMPO4F Sodium Fluorophosphates (M = Fe, V, Mn etc.) US
6872492
Na3M2(PO4)2F3 Sodium Fluorophosphates (M = Fe, V, Mn etc.)
US 6872492
LiMTiO4, LiMZrO4 Titanates, Zirconates (M = Fe, V, Mn etc.)
US 6720112
Li2MTiO4, Li2MZrO4 Titanates, Zirconates (M = Fe, Mn, Co,
Ni etc.) US 6103419
Li2CuO2 Lithium Copper Oxide US 5670277
LixMoO2 Lithium Molybdenum Oxides US 6908710
LiV2O5 Lithium Vanadium Oxide
Novel Phase A US Pending
Novel Phase B US Pending
Novel Phase C US Pending
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